I love that idea.
The movie "The Searchers" with John Wayne has a similar theme. After all that search, we discover that the niece has grown to be closer to her kidnapper who raised her than her biological family.
Another possibility would have both brothers making very different choices for the same reason.
Two identical brothers, same background, same education, two completely different choices lead to two completely different lives. Something bad happening to their shared love interest (injury, rape, ...) could be the reason. While being apart, they are still close together as both brothers still compete for the love and affection of that woman. Both trying to support her using their own personal situation. The pirate by smuggling drugs and weapons. The villager by bringing food. Until the big showdown.
There is a French book about that same situation during the Second World War between two brothers. One is resistant, the other is a collaborate ur. When one killed, the other one decide to assume both identity. In order to restore their brotherhood and avenge his brother, he erase (kills) all the person involved in their lives. Their shared love interest is the only one who at the end realise what is going on, but We the reader never find out which one was killed.